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Flowering plants use a pseudoenzyme to form indole

https://www.ice.mpg.de/496511/PR_Florean?c=95868

A catalytically inactive enzyme enables the formation of free indole for plant defense and communication. • Indole biosynthesis occurs via a pseudoenzyme: Although TSB-like is essential for indole formation, it does not have its own enzyme activity, unlike the enzymes TSB and TSA, which are active in the catalysis of indole to tryptophan.
different enzymes that could be involved in the crucial indole synthesis step using the model

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